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Zinc nitride : ウィキペディア英語版
Zinc nitride

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Zinc nitride (Zn3N2) is an inorganic compound of zinc and nitrogen. In pure form, it is cubic in structure.
==Chemical properties==
Zinc nitride can be obtained by thermally decomposing zincamide (zinc diamine) in an anaerobic environment, at temperatures in excess of 200 °C. The by-product of the reaction is ammonia.
3Zn(NH2)2 → Zn3N2 + 4NH3

It can also be formed by heating zinc to 600 °C in a current of ammonia; the by-product is hydrogen gas.〔〔

3Zn + 2NH3 → Zn3N2 + 3H2

Zinc nitride reacts violently with water to form ammonia and zinc oxide.〔〔
Zn3N2 + 3H2O → 3ZnO + 2NH3

It is soluble in hydrochloric acid
〕 and "reversibly reacts with lithium electrochemically".
Like magnesium nitride (Mg3N2) and lithium nitride (Li3N), it has a high melting point.

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